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Updated: May 20, 2026
Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
Published on: February 11, 2012
The first ionothermal synthesis of a germanium phosphate with one-dimensional chain-like structure
1Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi, PR China.
Abstract:
A novel germanium phosphate with a chain-like framework constructed from GeO(4)N(2) octahedra and PO(4) tetrahedra, [NH(4)](2)[Ge(NH(3))(2)(PO(4))(2)]·0.38H(2)O, was first synthesized via in situ decomposition of urea from ionic eutectic mixtures comprising urea and quaternary ammonium salts.
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