Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Metallic Solids02:37

Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Network Covalent Solids02:18

Network Covalent Solids

Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Bonding in Metals02:32

Bonding in Metals

Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Harmonized <sup>1</sup>H NMR Workflow Enables Quantitative Betaine Determination from Nontargeted Metabolite Profiling Using Internal and External Standards<sup>‡‡‡‡‡</sup>.

Analytical chemistry·2026
Same author

Pt(II) single sites in mixed-metal ZIF-8/67 <i>versus</i> PtAuCo@ZIF-67 for electrocatalytic methanol oxidation in fuel cells.

Dalton transactions (Cambridge, England : 2003)·2026
Same author

Chemical characterization of weathered polyethylene microplastics in marine coastal waters using OPLS-DA technique and ATR FT-IR spectra.

Marine pollution bulletin·2026
Same author

2D black phosphorus as a phosphide source for the formation of mixed cobalt phosphide clusters active in photocatalytic hydrogen evolution.

Nanoscale·2026
Same author

Functional <i>D</i>- and <i>L</i>‑Naphthalenediimide-Peptides: Microwave-Driven Synthesis, Supramolecular Aggregation, and Multiphoton Fluorescence Lifetime Imaging Microscopy in Living Cells.

ACS bio & med chem Au·2025
Same author

Advances in food metabolomics: Validating NMR-based non-targeted methods and fostering collaborative NMR applications.

Progress in nuclear magnetic resonance spectroscopy·2025

Related Experiment Video

Updated: May 20, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
14:07

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

Solution and solid-state dynamics of metal-coordinated white phosphorus.

Vincenzo Mirabello1, Maria Caporali, Vito Gallo

  • 1Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (ICCOM-CNR), Via Madonna del Piano 10, 50019, Sesto Fiorentino, Firenze, Italy.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|August 1, 2012
PubMed
Summary

This study reveals that tetraphosphorus ligands in transition metal complexes exhibit dynamic behavior, including rotation and tumbling, in both solution and solid states. These dynamic processes are crucial for understanding the ligand

More Related Videos

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
10:42

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

Published on: December 29, 2016

Related Experiment Videos

Last Updated: May 20, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
14:07

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
10:42

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

Published on: December 29, 2016

Area of Science:

  • Organometallic Chemistry
  • Solid-State Chemistry
  • Spectroscopy

Background:

  • Transition metal complexes with phosphorus ligands are vital in catalysis and materials science.
  • Understanding the dynamic behavior of ligands provides insights into reaction mechanisms and material properties.

Purpose of the Study:

  • To investigate the dynamic behavior of mono-hapto tetraphosphorus transition metal complexes in solution and solid states.
  • To elucidate the molecular motions and activation parameters governing these dynamic processes.

Main Methods:

  • Variable-temperature (VT) Nuclear Magnetic Resonance (NMR) spectroscopy.
  • 31P{(1)H} exchange spectroscopy (EXSY).
  • Magic Angle Spinning (MAS) NMR spectroscopy for solid-state analysis.

Main Results:

  • Mononuclear tetraphosphorus complexes exhibit ligand rotation and tumbling.
  • Binuclear complexes show metal migration between phosphorus atoms of the tetraphosphorus ligand.
  • Dynamic processes observed in solution were also detected in the solid state for specific complexes.
  • Activation parameters for dynamic processes and X-ray structures were determined.

Conclusions:

  • Metal-coordinated tetraphosphorus ligands are dynamic in both solution and solid states.
  • Ligand dynamics are influenced by metal type and co-ligands.
  • These findings challenge the view of metal-coordinated tetraphosphorus as a static ligand.