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Updated: May 19, 2026

Aerosol-assisted Chemical Vapor Deposition of Metal Oxide Structures: Zinc Oxide Rods
Published on: September 14, 2017
Activation of carbon dioxide over zinc oxide by localised electrons
Gargi Dutta1, Alexey A Sokol, C Richard A Catlow
1Department of Chemistry, Kathleen Lonsdale Materials Chemistry, University College London, United Kingdom.
Abstract:
The unique mechanism of activation of carbon dioxide over zinc oxide is unravelled using advanced quantum mechanical methods. The key process is the CO(2) chemisorption catalysed by a highly localized electron carrier trapped at a vacant oxygen interstitial surface site. At the top of the reaction barrier CO(2) pulls the electron from the vacancy and thus becomes active.
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