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Electrical-field-induced structural change and charge transfer of lanthanide-salophen complexes assembled on carbon

Gurvan Magadur1, Fatima Bouanis, Evgeny Norman

  • 1Institut de Chimie Moléculaire et des Matériaux d'Orsay, Université Paris Sud 11, CNRS, Bât. 420, 15 rue Georges Clemenceau, 91405 Orsay Cedex, France. gurvan.magadur@u-psud.fr

Chemical Communications (Cambridge, England)
|August 7, 2012
PubMed

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...