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Heterogeneous Catalysis01:22

Heterogeneous Catalysis

Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide02:44

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
Microbes and Methanogenesis01:26

Microbes and Methanogenesis

Methanogenesis is a critical microbial process in anaerobic ecosystems responsible for the biological production of methane, a potent greenhouse gas and valuable biofuel. This metabolic pathway is primarily facilitated by methanogenic archaea, which thrive in anoxic environments such as wetlands, sediments, and animal gastrointestinal tracts. The absence of oxygen in these habitats prevents aerobic respiration, thereby favoring alternative biochemical pathways for organic matter degradation.In...
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate02:21

Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate

Alkenes can be dihydroxylated using potassium permanganate. The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.
Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes02:14

Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes

The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were  initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified petroleum gas (LPG), fuel oil, gasoline, diesel fuel, and...

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Related Experiment Video

Updated: May 19, 2026

Temperature-programmed Deoxygenation of Acetic Acid on Molybdenum Carbide Catalysts
08:15

Temperature-programmed Deoxygenation of Acetic Acid on Molybdenum Carbide Catalysts

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Exceptional activity for methane combustion over modular Pd@CeO2 subunits on functionalized Al2O3.

M Cargnello1, J J Delgado Jaén, J C Hernández Garrido

  • 1Department of Chemical and Pharmaceutical Sciences, ICCOM-CNR, Consortium INSTM, University of Trieste, via L. Giorgieri 1, 34127 Trieste, Italy.

Science (New York, N.Y.)
|August 11, 2012
PubMed
Summary

Researchers developed a novel catalyst for methane oxidation. This palladium-ceria catalyst offers high activity below 400°C and excellent thermal stability, crucial for reducing greenhouse gas emissions.

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Area of Science:

  • Catalysis
  • Materials Science
  • Environmental Science

Background:

  • Methane is a potent greenhouse gas with significant emissions.
  • Current methane oxidation catalysts lack activity below 400°C or thermal stability.
  • Improved catalysts are needed for emission reduction and gas turbine performance.

Purpose of the Study:

  • To develop a novel methane oxidation catalyst with high activity and stability.
  • To address limitations of existing catalysts for greenhouse gas mitigation.

Main Methods:

  • Supramolecular assembly of palladium (Pd) core and ceria (CeO2) shell units.
  • Homogeneous deposition onto modified hydrophobic alumina support.
  • Characterization using electron microscopy and structural analysis.

Main Results:

  • Isolated Pd cores within CeO2 shells were achieved, stable up to 850°C.
  • Enhanced metal-support interactions were observed.
  • Complete methane conversion below 400°C was demonstrated.

Conclusions:

  • The novel Pd-CeO2 catalyst exhibits exceptional methane oxidation activity and thermal stability.
  • This supramolecular approach offers a promising strategy for designing advanced oxidation catalysts.
  • The catalyst can contribute to reducing methane emissions and improving gas turbine efficiency.