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The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF
Chengbing Qin1, Ruohan Zhang, Fang Wang
1Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287-1604, USA.
Abstract:
The [11.9]Ω = 3/2 ← X (2)Π(3/2)(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The (19)F(I = 1/2) and (195)Pt(I = 1/2) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μ(el), of 2.47(11)D and 3.42(6)D for the [11.9]Ω = 3/2 and X (2)Π(3/2)states, respectively. The observed trend in μ(el) for the PtX (X = C,N,O,S and F) series is discussed and a comparison with IrF made.
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