Spectroscopic analyses of pollutants in water, sediment and fish

Water ways in Egypt is suffering from continual discharge without adequate treatment especially in the Delta and greater Cairo area. Accordingly water, sediments and catfishes were collected from El Mouheet El Youmna drain in Giza. Cd, Cr, Pb and Zn were determined furthermore the molecular structure of sediment and catfish were conducted with FTIR spectroscopy. Although studied metals were lower in water, higher values are recorded in sediment and catfish samples. FTIR shows possible interaction among metals and organic structures mainly proteins. The bioaccumulation of Pb and Cd proportion was significantly increased in the liver tissues of catfish. A correlation coefficient among sediment and fish liver metals accumulation exist. This infers that the waste assimilation capacity for the drain is high, a phenomena that could be ascribed to dilution, sedimentation and continual water exchange. Furthermore, the genotoxicity affect in catfish genomic corroborates the genus diagnostic markers which attributed to long pollution. This is an indication that agriculture and industrial wastes discharged into the drain has badly a significant effect on the ecological balance.