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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Tris(ethyl-enediamine-κ(2)N,N')nickel(II) bis-(dimethyl phosphate)
Masoud Rafizadeh1, Hamid Reza Saadati Moshtaghin, Vahid Amani
1Department of Chemistry, Share-Ray Branch, Islamic Azad University, Tehran, Iran.
Acta Crystallographica. Section E, Structure Reports Online
|August 21, 2012
Abstract:
In the title compound, [Ni(C(2)H(8)N(2))(3)][O(2)P(OCH(3))(2)](2), the Ni(II) atom is six-coordinated in a distorted octa-hedral geometry by six N atoms from three ethyl-enediamine ligands. The P atoms of the anions adopt a distorted tetra-hedral geometry. In the crystal, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the cations and anions into a three-dimensional network.

