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Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules
Published on: April 28, 2014
Poly[aqua-[μ-1,2-bis-(pyridin-4-yl)ethene-κ(2)N:N'][μ-5-(diphenyl-phosphino-yl)iso-phthalato-κ(3)O(1),O(1'):O(3)]nick
Acta Crystallographica. Section E, Structure Reports Online
|August 21, 2012
Abstract:
In the title compound, [Ni(C(20)H(13)O(5)P)(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) cation is coordinated by three O atoms from two 5-(diphenyl-phosphino-yl)isophthalate anions, two N atoms from two 1,2-bis-(pyridin-4-yl)ethene ligands and one water mol-ecule in a distorted octa-hedral geometry. Both 1,2-bis-(pyridin-4-yl)ethene and 5-(diphenyl-phosphino-yl)iso-phthal-ate bridge the Ni(II) cations to form polymeric layers parallel to (001). In the crystal, O-H⋯O hydrogen bonding links layers into a three-dimensional supra-molecular structure.
