trans-Bis[1-(2-benzamido-eth-yl)-3-(2,4,6-trimethyl-phen-yl)imidazol-2-yl-idene]dichloridopalladium(II)
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Updated: May 19, 2026
![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
Stefan Warsink1, Andreas Roodt
1Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein, South Africa.
Abstract:
In the title compound, [PdCl(2)(C(21)H(23)N(3)O)(2)], the Pd(II) atom is located on an inversion centre and is coordinated in a slightly distorted square-planar environment by the chloride and N-heterocyclic carbene (NHC) ligands in mutual trans positions. There are several hydrogen-bonding inter-actions, the most significant of which is a hydrogen bond between the amide moiety of the NHC and the chloride ligand. These hydrogen-bond interactions form a three-dimensional network.
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