(Acetyl-acetonato-κ(2)O,O')bis-{5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl-κ(2)N(1),C(1)}iridium(III)
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Updated: May 19, 2026
The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
1State Key Laboratory Base of Novel Functional Materials and Preparation Science, Institute of Solid Materials Chemistry, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.
Abstract:
In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl ligands and one O,O'-bidentate acetyl-acetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)°.
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