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Updated: May 19, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Di-μ-acetato-κ(4)O:O-bis-({N'-[(E)-phen-yl-(pyridin-2-yl-κN)methyl-idene]benzo-hydrazidato-κ(2)N',O}copper(II))
Abstract:
The binuclear molecule of the title compound, [Cu(2)(C(19)H(14)N(3)O)(2)(CH(3)COO)(2)], resides on a crystallographic inversion centre. It has an E conformation with respect to the azomethine double bond and a Z conformation about the amide C=N bond. The Cu(II) atom has a slightly distorted square-pyramidal coordination geometry. The crystal packing involves inter-molecular C-H⋯O, C-H⋯N and C-H⋯π and two types of π-π inter-actions, with centroid-centroid distances of 3.9958 (10) and 3.7016 (13) Å.
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