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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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2-Chloro-1-(4-hy-droxy-phen-yl)ethanone
Acta Crystallographica. Section E, Structure Reports Online
|August 21, 2012
Abstract:
The asymmetric unit of the title compound, C(8)H(7)ClO(2), consists of two independent mol-ecules, with comparable geometries. Both mol-ecules are approximately planar (r.m.s. deviations = 0.040 and 0.064 Å for the 11 non-H atoms). In the crystal, mol-ecules are linked via inter-molecular O-H⋯O and C-H⋯O hydrogen bonds into chains two mol-ecules thick along (-101).
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