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Updated: May 19, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
(R,E)-3-(4-Chloro-phen-yl)-1-phenyl-allyl 4-nitro-benzoate
Konstantin Troshin1, Peter Mayer, Herbert Mayr
1Ludwig-Maximilians-Universität, Department, Butenandtstrasse 5-13, 81377 München, Germany.
Abstract:
The title compound, C(22)H(16)ClNO(4), adopts a conformation in which the phenyl ring plane forms similar dihedral angles with the nitro-benzoate C(6) ring [76.97 (8)°] and the chloro-phenyl group [76.95 (8)°]; the dihedral angle between the chloro-phenyl and nitro-benzoate rings is 66.43 (8)°. In the crystal, π-π stacking is observed between the latter two planes, with a dihedral angle of 1.79 (8)° and a centroid-centroid distance of 3.735 (1) Å. In addition, mol-ecules are linked along [100] by weak C-H⋯O contacts.
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