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Related Concept Videos

Ferromagnetism01:31

Ferromagnetism

Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
Colors and Magnetism03:02

Colors and Magnetism

Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
Magnetic Susceptibility and Permeability01:31

Magnetic Susceptibility and Permeability

In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
Diamagnetism01:26

Diamagnetism

Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets.
Lattice Energies of Ionic Crystals01:27

Lattice Energies of Ionic Crystals

Lattice energy represents the energy released when gaseous cations and anions combine to form an ionic solid, reflecting the strength of electrostatic interactions within the crystal. This process is fundamentally governed by Coulombic attraction between oppositely charged ions, where the potential energy varies inversely with the interionic distance and directly with the product of ionic charges. As ions approach one another, the electrostatic energy becomes increasingly negative, indicating a...

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Related Experiment Video

Updated: May 19, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
08:55

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses

Published on: June 7, 2018

Magnetic correlations in a layered iridate, Na2IrO3.

S W Lovesey1, A N Dobrynin

  • 1ISIS Facility, STFC, Didcot, Oxfordshire, UK. stephen.lovesey@stfc.ac.uk

Journal of Physics. Condensed Matter : an Institute of Physics Journal
|August 29, 2012
PubMed
Summary

Researchers studied sodium iridate (Na2IrO3) in its antiferromagnetic state. Iridium magnetic moments were found to lie in the a-c plane, revealing details about its magnetic ground state.

Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Crystallography

Background:

  • Sodium iridate (Na2IrO3) is a material exhibiting complex magnetic properties.
  • Understanding the magnetic ordering in such materials is crucial for developing novel electronic devices.

Purpose of the Study:

  • To determine the precise orientation of iridium magnetic dipole moments in Na2IrO3.
  • To establish a plausible magnetic ground state for Na2IrO3 based on experimental data.

Main Methods:

  • Analysis of published data from resonant x-ray Bragg diffraction measurements.
  • Integration of diffraction data with existing bulk magnetic measurements.

Main Results:

  • Iridium magnetic dipole moments are confined to the a-c plane of the monoclinic crystal structure.

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Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
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Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals

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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses

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Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
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Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals

Published on: April 14, 2020

  • An angle of approximately 118° was measured between the magnetic moments and the c-axis.
  • A magnetic space group, compatible with antiferromagnetic order, was proposed, with magnetic dipoles perpendicular to the b-axis.
  • Conclusions:

    • The study elucidates the magnetic structure of Na2IrO3 at low temperatures.
    • Predicted anapoles (toroidal dipoles) are also confined to the a-c plane.
    • Magnetic charges are forbidden in this magnetic ground state.