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Updated: May 19, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
A two-dimensional coordination polymer containing a two-dimensional zinc-carboxylate layer constructed from helical
Wei-Lu Xiong1, Qing-Yan Liu, Na Zhang
1College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, Jiangxi 330022, People's Republic of China.
Abstract:
The title compound, [Zn(C(8)H(4)O(4))](n), consists of one Zn(II) cation and one benzene-1,2-dicarboxylate dianion (BDC(2-)) as the building unit. The Zn(II) cation is four-coordinated by four carboxylate O atoms from four dianionic BDC(2-) ligands in a distorted tetrahedral geometry. The Zn(II) cations are linked by the BDC(2-) ligands to generate a structure featuring two-dimensional zinc-carboxylate layers containing left- and right-handed helical chains. The two-dimensional layers are stacked along the a direction. The thermal stability of the title compound has been studied.
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