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Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Differentiation of highly anisotropic TbIII and DyIII with 57Fe Mössbauer spectroscopy
1Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Karlsruhe, Germany. valeriu.mereacre@kit.edu
Angewandte Chemie (International Ed. in English)
|September 5, 2012
Abstract:
Using (57)Fe Mössbauer spectroscopy, three examples of coordination compounds with different topologies containing Fe(III) and Ln(III) ions (Dy(III) and Tb(III); see diagram; insets: clusters cores) were analyzed. In the same crystal field environment, Dy and Tb ions show different degrees of anisotropy, which can be qualitatively detected using an indirect method.
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