Related Experiment Video
Updated: May 19, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Published on: December 29, 2016
Aqueous alkali-metal silicate anions containing fully condensed four-coordinate sites
Christopher T G Knight1, Raymond J Balec, Stephen D Kinrade
1School of Chemical Sciences, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA.
Abstract:
Conspicuous absence: (29)SiNMR studies show that highly condensed, four-coordinate Si-containing anions are common in concentrated alkali-metal silicate solutions, but reveal no evidence for the existence of specialized zeolite building units. The results add to the mounting evidence that silicate polymerization simply proceeds through stepwise condensation of monosilicate tetrahedra.
Related Concept Videos
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Alkali Metals
Table 1: Properties of the alkali metals
Ionic Compounds: Formulas and Nomenclature
Ionic Bonding and Electron Transfer
Ions as Acids and Bases
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Complexation Equilibria: Factors Influencing Stability of Complexes

