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Related Experiment Video

Updated: May 18, 2026

Measurement of Aerosols Optical Thickness of the Atmosphere using the GLOBE Handheld Sun Photometer
06:27

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Evidence for NO(x) control over nighttime SOA formation.

A W Rollins1, E C Browne, K-E Min

  • 1Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, USA.

Science (New York, N.Y.)
|September 8, 2012
PubMed
Summary
This summary is machine-generated.

Nighttime formation of organic aerosol (OA) in Bakersfield increases with nitrogen oxides (NOx). Reductions in NOx emissions are expected to decrease OA concentrations in the region.

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Area of Science:

  • Atmospheric chemistry
  • Aerosol science
  • Environmental science

Background:

  • Laboratory studies show nitrogen oxides (NOx) influence atmospheric organic aerosol (OA) production through various chemical pathways.
  • Direct observation of these NOx effects on ambient OA has been limited.

Purpose of the Study:

  • To investigate the direct impact of nitrogen oxides (NOx) on ambient organic aerosol (OA) formation.
  • To quantify the contribution of specific chemical pathways to nighttime OA production.

Main Methods:

  • Measurements of particulate organic nitrates were conducted in Bakersfield, California.
  • Analysis focused on the relationship between NOx concentrations and the formation of organic nitrates.
  • Investigated the suppression effects of reactive organic molecules on nitrate radical (NO3) chemistry.

Main Results:

  • Nighttime organic nitrate formation was observed to increase with NOx concentrations.
  • High concentrations of reactive organic molecules suppressed organic nitrate formation, indicating multigenerational chemistry.
  • Organic nitrates accounted for approximately one-third of the nighttime increase in OA.

Conclusions:

  • Multigenerational chemistry driven by the nitrate radical (NO3), a product of anthropogenic NOx emissions, is a significant source of nighttime secondary OA.
  • Reducing NOx emissions in Bakersfield and surrounding areas should lead to decreased organic aerosol concentrations.