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C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions
1UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California Riverside, Riverside, CA 92521-0403, USA.
Chemistry (Weinheim an Der Bergstrasse, Germany)
|September 11, 2012
Abstract:
F-act finding mission: Selective activation of the para C-F bonds of perfluorinated aromatic derivatives was achieved with a simple ethynyl dithiocarbamate. The resulting adducts can be used as non-ionic, anhydrous fluoride transfer reagents towards various electrophiles (see scheme).