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Updated: May 18, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2)N(1):N(4))amino-meth-yl]phenol] nitrate]
Abstract:
The Ag(I) atom in the polycationic salt, {[Ag(C(11)H(11)N(3)O)]NO(3)}(n), shows a linear coordination [N-Ag-N = 175.0 (2)°]; the polymeric nature arises from bridging by the pyrazine portion of the ligand, resulting in chains extending parallel to [100]. The NO(3) (-) counter-ions surround the polymeric chain and inter-act only weakly with it [Ag⋯O = 2.701 (4) and 2.810 (5) Å]. Adjacent chains are linked into a three-dimensional network by O-H⋯O and N-H⋯O hydrogen bonds.
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