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Updated: May 18, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
trans-Dichloridotetra-pyrazine-ruthenium(II) dichloro-methane disolvate
Abstract:
In the title compound, [RuCl(2)(C(4)H(4)N(2))(4)]·2CH(2)Cl(2), the Ru(II) atom occupies a position of 222 symmetry and the C atom of the solvent mol-ecule occupies a site with twofold symmetry. The Ru(II) atom has a slightly distorted octa-hedral geometry. The pyrazine rings are propeller-like and rotated 45.1 (1)° from the RuN(4) plane. In the crystal, the complex and solvent mol-ecules are bridged by weak C-H⋯N hydrogen bonds along the c axis. Weak inter-molecular C-H⋯Cl contacts link the complexes in the ab plane, forming a network.
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