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Updated: May 18, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Trichlorido[4-meth-oxy-2,6-bis-(2-pyrimidin-2-yl-κN)phenyl-κC(1)]platinum(IV) acetonitrile monosolvate
Abstract:
In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa-hedral coordination geometry defined by a tridentate cyclo-metalated NCN ligand and three Cl atoms. In the crystal, individual mol-ecules are aggregated into a three-dimensional network by C-H⋯Cl hydrogen-bonding inter-actions and π-π stacking inter-actions between the tridentate ligands, the shortest ring centroid-centroid distance being 3.613 Å.
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