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A new sesquiterpene glucoside from Nicotiana rustica L

Rong Zhou1, Dong-Liang Li, Guang-Lin Feng

  • 1Technology R&D Center, China Tobacco Chuanyu Industrial Co. Ltd, Chengdu 610066, China.

Natural Product Research
|September 15, 2012
PubMed

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Nitriles to Ketones: Grignard Reaction00:57

Nitriles to Ketones: Grignard Reaction

Organomagnesium halides, commonly known as Grignard reagents, convert nitriles to ketones and proceed through a nucleophilic acyl substitution. Nitriles react with a Grignard reagent, followed by an aqueous acid, to yield ketones. The reaction introduces a new carbon–carbon bond. The alkyl–magnesium bond in the Grignard reagent is highly polar, so the alkyl carbon develops a carbanionic character and acts as a nucleophile.
The mechanism begins with a nucleophilic attack by the Grignard reagent...