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Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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Published on: February 7, 2019

Pd-catalyzed borylative cyclisation of 1,7-enynes

Virtudes Pardo-Rodríguez1, Elena Buñuel, Daniel Collado-Sanz

  • 1Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049-Madrid, Spain.

Chemical Communications (Cambridge, England)
|September 21, 2012
PubMed
Summary

This study introduces a new palladium-catalyzed reaction using 1,7-enynes and bis(pinacolato) diboron. The process efficiently synthesizes valuable six-membered cyclic homoallylic and allylic boronates.

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