Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Phase Transitions: Vaporization and Condensation02:39

Phase Transitions: Vaporization and Condensation

The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules...
¹H NMR: Interpreting Distorted and Overlapping Signals01:02

¹H NMR: Interpreting Distorted and Overlapping Signals

Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are slanted or...
Phase Transitions: Sublimation and Deposition02:33

Phase Transitions: Sublimation and Deposition

Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
Modes of Standing Waves: II01:04

Modes of Standing Waves: II

The starting point for expressing the modes of standing waves is understanding the boundary conditions that the waves must follow. The boundary conditions are derived from the physical understanding of how the standing waves are sustained, that is, how the vibrating particles of the medium behave at the boundaries imposed on them.
For a tube open at one end and closed at the other filled with air, the modes are such that there is always an antinode at the open end and a node at the closed end.
Atomic Nuclei: Nuclear Spin State Overview01:03

Atomic Nuclei: Nuclear Spin State Overview

NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of one, the...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Theory of temporal pattern learning in echo state networks.

PNAS nexus·2026
Same author

Phase-field approach to cellular blebbing.

Physical review. E·2026
Same author

Phase-field model of freeze casting.

Physical review. E·2026
Same author

Parity breaking at faceted crystal growth fronts during ice templating.

Physical review. E·2026
Same author

Quantification and prediction of solidification textures under additive manufacturing conditions.

Nature communications·2025
Same author

The mechanism of nesprin-2 accumulation at the nucleus front during confined cell migration.

Biophysical journal·2025

Related Experiment Video

Updated: May 18, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
11:03

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids

Published on: December 4, 2017

Surface modes of coherent spinodal decomposition.

Ming Tang1, Alain Karma

  • 1Condensed Matter and Materials Division, Lawrence Livermore National Laboratory, Livermore, California 94550, USA. tang25@llnl.gov

Physical Review Letters
|September 26, 2012
PubMed
Summary

Free surfaces accelerate phase separation in solids through unique surface spinodal decomposition modes. This alters metastability limits, even when bulk decomposition is suppressed, impacting material stability.

More Related Videos

Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System
08:19

Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System

Published on: May 9, 2021

Experimental Methods for Spin- and Angle-Resolved Photoemission Spectroscopy Combined with Polarization-Variable Laser
09:00

Experimental Methods for Spin- and Angle-Resolved Photoemission Spectroscopy Combined with Polarization-Variable Laser

Published on: June 28, 2018

Related Experiment Videos

Last Updated: May 18, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
11:03

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids

Published on: December 4, 2017

Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System
08:19

Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System

Published on: May 9, 2021

Experimental Methods for Spin- and Angle-Resolved Photoemission Spectroscopy Combined with Polarization-Variable Laser
09:00

Experimental Methods for Spin- and Angle-Resolved Photoemission Spectroscopy Combined with Polarization-Variable Laser

Published on: June 28, 2018

Area of Science:

  • Materials Science
  • Solid-State Physics
  • Chemical Engineering

Background:

  • Spontaneous phase separation in solids is crucial for material properties.
  • Misfit stress influences phase separation kinetics in elastically coherent solids.
  • Free surfaces can alter bulk material behavior due to stress relaxation.

Purpose of the Study:

  • To investigate the impact of free surfaces on spontaneous phase separation in elastically coherent solids.
  • To understand how surface effects modify spinodal decomposition kinetics and metastability limits.
  • To compare surface-mediated phase separation with bulk spinodal decomposition.

Main Methods:

  • Linear stability theory.
  • Numerical simulations.
  • Analysis of surface and bulk spinodal decomposition modes.

Main Results:

  • Free surfaces fundamentally alter spontaneous phase separation.
  • Unique surface modes of spinodal decomposition exhibit faster kinetics than bulk modes.
  • Surface modes remain unstable even when bulk spinodal decomposition is suppressed.
  • The limit of metastability shifts from coherent to chemical spinodal in the presence of free surfaces.

Conclusions:

  • Free surfaces introduce novel mechanisms for phase separation in solids.
  • Surface spinodal decomposition can dominate over bulk processes, especially near metastability limits.
  • Understanding surface effects is critical for controlling phase separation and material properties in crystalline materials.