Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Imperfections in Crystal Structure: Point, Line and Plane Defects01:25

Imperfections in Crystal Structure: Point, Line and Plane Defects

A perfect crystal, in theory, has a uniform structure with the same unit cell and lattice points throughout. However, any deviation from this periodic arrangement is known as an imperfection or defect. These defects can be categorized into three types: point, line, and plane defects.Point defects occur when there is a deviation from the ideal due to missing atoms, displaced atoms, or additional atoms. These imperfections might occur due to imperfect packing during crystallization or because of...
Imperfections in Crystal Structure: Stoichiometric Point Defects01:26

Imperfections in Crystal Structure: Stoichiometric Point Defects

Schottky defects arise when some lattice points in a crystal, such as those in NaCl, remain unoccupied, creating lattice vacancies without disturbing the overall electrical neutrality of the crystal. This defect is common in ionic crystals where the positive and negative ions are similar in size, as seen in sodium chloride and cesium chloride. The presence of Schottky defects enables the crystal to conduct electricity to a small extent through an ionic mechanism. Electric fields cause nearby...
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Imperfections in Crystal Structure: Non-Stoichiometric Defects01:29

Imperfections in Crystal Structure: Non-Stoichiometric Defects

Non-stoichiometric defects refer to a type of defect in the crystal structure of a compound where the ratio of its constituent elements deviates from the ideal stoichiometric ratio. There are two main types of non-stoichiometric defects: metal excess defects and metal deficiency defects.Metal excess defects occur when there is a slight surplus of metal ions than what is required by the stoichiometric ratio of the compound. For example, heating a sodium chloride crystal in sodium vapor results...
Structures of Solids02:22

Structures of Solids

Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Low- Temperature Transformations in Amorphous Silica Bilayers on Ru(0001) After Crystal-Glass Transition: Closer Look.

Chemistry (Weinheim an der Bergstrasse, Germany)·2025
Same author

Writing with Molecules: Tip-Induced Local Chemisorption of N-Heterocyclic Olefins on Cu(111).

Journal of the American Chemical Society·2025
Same author

Structure Sensitivity and Catalyst Restructuring for CO<sub>2</sub> Electro-reduction on Copper.

Nature communications·2025
Same author

Growth and Structure of Ultrathin Iron Silicate and Iron Germanate Films.

The journal of physical chemistry. C, Nanomaterials and interfaces·2024
Same author

Polarisationsabhängige Summenfrequenzspektroskopie (SFG) zur in situ Bestimmung der Nanopartikel-Morphologie.

Angewandte Chemie (Weinheim an der Bergstrasse, Germany)·2024
Same author

The Influence of Mesoscopic Surface Structure on the Electrocatalytic Selectivity of CO<sub>2</sub> Reduction with UHV-Prepared Cu(111) Single Crystals.

ACS energy letters·2024

Related Experiment Video

Updated: May 18, 2026

On-Chip Crystallization and Large-Scale Serial Diffraction at Room Temperature
07:42

On-Chip Crystallization and Large-Scale Serial Diffraction at Room Temperature

Published on: March 11, 2022

Crystalline-vitreous interface in two dimensional silica.

Leonid Lichtenstein1, Markus Heyde, Hans-Joachim Freund

  • 1Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany.

Physical Review Letters
|September 26, 2012
PubMed
Summary
This summary is machine-generated.

Researchers studied the transition between crystalline and vitreous silica using low-temperature scanning tunneling microscopy. They observed that crystalline order gradually fades over 1.6 nm into the vitreous state.

More Related Videos

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
06:26

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets

Published on: May 15, 2017

Preparation of Macroporous Epitaxial Quartz Films on Silicon by Chemical Solution Deposition
07:37

Preparation of Macroporous Epitaxial Quartz Films on Silicon by Chemical Solution Deposition

Published on: December 21, 2015

Related Experiment Videos

Last Updated: May 18, 2026

On-Chip Crystallization and Large-Scale Serial Diffraction at Room Temperature
07:42

On-Chip Crystallization and Large-Scale Serial Diffraction at Room Temperature

Published on: March 11, 2022

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
06:26

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets

Published on: May 15, 2017

Preparation of Macroporous Epitaxial Quartz Films on Silicon by Chemical Solution Deposition
07:37

Preparation of Macroporous Epitaxial Quartz Films on Silicon by Chemical Solution Deposition

Published on: December 21, 2015

Area of Science:

  • Materials Science
  • Solid State Physics
  • Surface Science

Background:

  • Thin metal-supported silica films exhibit complex interfacial properties.
  • Understanding the crystalline-vitreous transition is crucial for materials design.

Purpose of the Study:

  • To investigate the structural evolution at the crystalline-vitreous interface in silica films.
  • To analyze changes in Si-Si distances, angles, and ring size distribution across the transition zone.

Main Methods:

  • Low-temperature scanning tunneling microscopy (LT-STM) was employed.
  • Local atomic distances and characteristic angles were measured.
  • Ring size distribution was analyzed near the transition.

Main Results:

  • The crystalline order was observed to decay gradually over approximately 1.6 nm.
  • Si-Si nearest neighbor distances and characteristic angles evolved across the interface.
  • Changes in ring size distribution were identified near the crystalline-vitreous transition.

Conclusions:

  • The crystalline-vitreous transition in silica films is a gradual process.
  • LT-STM provides high-resolution insights into interfacial structural dynamics.
  • The findings contribute to understanding amorphous material formation at interfaces.