Hot spots in density fingering of exothermic autocatalytic chemical fronts

Measurements of two-dimensional (2D) temperature fields are performed by an interferometric method during density fingering of the autocatalytic chlorite-tetrathionate reaction in a Hele-Shaw cell. These measures confirm that, because of heat losses through the glass walls of the reactor, the temperature profile across the front is a pulse rather than a front. Moreover, the full 2D temperature field shows the presence in the reactive zone of hot spots where the temperature exceeds the maximum temperature measured in a stable planar front. We investigate here experimentally the increase of temperature in the hot spots when the composition of the reactants is varied to increase the exothermicity of the reaction. We back up these experimental observations by nonlinear simulations of a reaction-diffusion-convection model which show that the maximum temperature reached in the system depends on the intensity of convection.