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Related Concept Videos

¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
¹H NMR: Interpreting Distorted and Overlapping Signals01:02

¹H NMR: Interpreting Distorted and Overlapping Signals

Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are slanted or...
Double Resonance Techniques: Overview01:12

Double Resonance Techniques: Overview

Double resonance techniques in Nuclear Magnetic Resonance (NMR) spectroscopy involve the simultaneous application of two different frequencies or radiofrequency pulses to manipulate and observe two distinct nuclear spins. One important application of double resonance is spin decoupling, which selectively suppresses coupling with one type of nucleus while observing the NMR signal from another nucleus, simplifying the spectrum and enhancing resolution.
Spin decoupling is usually achieved by...
Resonance and Hybrid Structures02:16

Resonance and Hybrid Structures

According to the theory of resonance, if two or more Lewis structures with the same arrangement of atoms can be written for a molecule, ion, or radical, the actual distribution of electrons is an average of that shown by the various Lewis structures.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
The de Broglie Wavelength02:32

The de Broglie Wavelength

In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
Resonance02:52

Resonance

The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N-O and N=O bonds.

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Related Experiment Video

Updated: May 18, 2026

Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems
07:44

Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems

Published on: April 28, 2016

Double resonance in the infinite-range quantum Ising model.

Sung-Guk Han1, Jaegon Um, Beom Jun Kim

  • 1Department of Physics and BK21 Physics Research Division, Sungkyunkwan University, Suwon 440-746, Korea.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|September 26, 2012
PubMed
Summary

We investigated quantum resonance in the kinetic Ising model. Two resonance peaks were observed near the quantum phase transition, suggesting this is a general feature of continuous transitions in many-body systems.

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Area of Science:

  • Quantum physics
  • Condensed matter theory
  • Statistical mechanics

Background:

  • The kinetic Ising model describes magnetic systems with quantum effects.
  • Understanding quantum resonance is crucial for characterizing many-body system dynamics.

Purpose of the Study:

  • To investigate quantum resonance behavior in the infinite-range kinetic Ising model at zero temperature.
  • To explore the impact of external magnetic fields on resonance phenomena.

Main Methods:

  • Numerical integration of the time-dependent Schrödinger equation.
  • Analysis of the system's response to an external magnetic field in the z-direction.
  • Varying transverse field strengths (g) to observe resonance effects.

Main Results:

  • Identified two distinct resonance peaks in the system's behavior.
  • These peaks occur when the energy gap aligns with the external driving frequency.
  • Resonance phenomena were observed at transverse field strengths both below and above the quantum phase transition.

Conclusions:

  • The occurrence of double resonance peaks is a generic feature of continuous phase transitions.
  • This phenomenon is expected in both quantum and classical many-body systems exhibiting such transitions.