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Related Concept Videos

Atomic Absorption Spectroscopy: Interference01:25

Atomic Absorption Spectroscopy: Interference

Interference leads to systematic error in atomic absorption (AA) measurements by enhancing or diminishing the analytical signal or the background. These interferences can be grouped into three main categories: spectral interference, chemical interference, and physical interference.
Spectral interference occurs when signals from other elements or molecules overlap with the analyte signal, falsely elevating or masking the analyte's absorbance. This interference can be corrected using Zeeman,...
Atomic Absorption Spectroscopy: Lab01:21

Atomic Absorption Spectroscopy: Lab

For AAS measurements, samples must be introduced as clear solutions, often requiring extensive preliminary treatment to dissolve materials like soils, animal tissues, and minerals. Common methods for sample preparation include treatment with hot mineral acids, wet ashing, combustion in closed containers, high-temperature ashing, or fusion with reagents.
 Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing nebulizer...
UV–Vis Spectrometers01:14

UV–Vis Spectrometers

The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell. Samples for...
Flame Photometry: Lab01:16

Flame Photometry: Lab

In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
Gas Chromatography: Types of Detectors-II01:19

Gas Chromatography: Types of Detectors-II

In gas chromatography, different detectors are employed to meet specific analytical needs. These detectors are often categorized based on their detection mechanisms and the types of compounds they are best suited to analyze. Thermal Conductivity Detectors (TCD), Flame Ionization Detectors (FID), and Electron Capture Detectors (ECD) represent common categories, each with unique operating principles and applications. However, beyond these, several other detectors are designed for more specialized...
Flame Photometry: Overview01:02

Flame Photometry: Overview

Flame photometry, also known as flame emission spectrometry, is a technique used for the qualitative and quantitative analysis of elements present in a sample using a flame as the source of excitation energy. The concept of flame photometry was realized in the early 1860s by Kirchhoff and Bunsen, who discovered that specific elements emit characteristic radiation when excited in flames. The first instrument developed for this purpose was used to measure sodium (Na) in plant ash using a Bunsen...

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Related Experiment Video

Updated: May 18, 2026

Measuring Dissolved Methane in Aquatic Ecosystems Using An Optical Spectroscopy Gas Analyzer
05:00

Measuring Dissolved Methane in Aquatic Ecosystems Using An Optical Spectroscopy Gas Analyzer

Published on: July 26, 2024

[Studies on the data processing method in chlorine measurement by differential optical absorption spectroscopy

Cong-Lei Ye1, Pin-Hua Xie, Min Qin

  • 1Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China. clye@aiofm.ac.cn

Guang Pu Xue Yu Guang Pu Fen Xi = Guang Pu
|September 29, 2012
PubMed
Summary

This study demonstrates that polynomial fitting accurately retrieves chlorine concentration using Differential Optical Absorption Spectroscopy (DOAS). This method offers a feasible and precise approach for chlorine detection.

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Dynamic Electrochemical Measurement of Chloride Ions
07:32

Dynamic Electrochemical Measurement of Chloride Ions

Published on: February 5, 2016

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Last Updated: May 18, 2026

Measuring Dissolved Methane in Aquatic Ecosystems Using An Optical Spectroscopy Gas Analyzer
05:00

Measuring Dissolved Methane in Aquatic Ecosystems Using An Optical Spectroscopy Gas Analyzer

Published on: July 26, 2024

Dynamic Electrochemical Measurement of Chloride Ions
07:32

Dynamic Electrochemical Measurement of Chloride Ions

Published on: February 5, 2016

Area of Science:

  • Atmospheric Chemistry
  • Spectroscopy
  • Analytical Chemistry

Context:

  • Accurate measurement of atmospheric pollutants is crucial for environmental monitoring.
  • Differential Optical Absorption Spectroscopy (DOAS) is a widely used technique for gas analysis.
  • Developing robust methods for chlorine detection is essential for industrial safety and environmental studies.

Purpose:

  • To evaluate the effectiveness of different data processing methods for chlorine detection using DOAS.
  • To compare triangle filtering and polynomial fitting for analyzing chlorine absorption spectra.
  • To determine the optimal polynomial order for accurate chlorine concentration retrieval.

Summary:

  • Experimental measurements of chlorine were conducted using a laboratory-built DOAS system.
  • Two methods, triangle filtering and polynomial fitting, were applied to standard chlorine cross-sections.
  • Fifth-order polynomial fitting demonstrated superior accuracy and linearity (0.9961) for chlorine retrieval compared to triangle filtering, with minimal spectral residuals.

Impact:

  • The study validates polynomial fitting as a feasible and accurate method for chlorine detection via DOAS.
  • This technique provides a reliable tool for monitoring chlorine concentrations in various settings.
  • The findings contribute to advancing spectroscopic methods for environmental and industrial gas analysis.