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Updated: May 17, 2026
Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Structural relaxation and quasi-elastic light scattering in glass: approach by ferroelectric and ion-conducting
Yoshihiro Takahashi1, Kensaku Nakamura, Minoru Osada
1Department of Applied Physics, Tohoku University, Aoba-ku, Sendai, Japan. takahashi@laser.apph.tohoku.ac.jp
Abstract:
Inelastic light scattering has been utilized for examining the structure of glass and its relaxation. However, the quasi-elastic-light-scattering (QLS) phenomenon has not been addressed in much detail. In this study, we observed pronounced QLS-intensity variations in two temperature domains-supercooled liquid (SCL) state (α-relaxation regime) and below the glass-transition temperature (β-relaxation regime)-in niobium-oxide (Nb(2)O(5))-rich glass. These variations may be interpreted on the basis of the concept of ferroelectric and ion-conducting phases. It was suggested that the observed QLS originates as a result of the polarization fluctuation of NbO(6) units, which is due to the dynamics of the nanometric phase separation in the SCL phase (α-regime), and the fluctuation due to the migration/hopping of conductible ions that are localized in the vicinity of the NbO(6) units (β-regime).
