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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Published on: March 20, 2014

Titanocene-catalyzed multicomponent coupling approach to diarylethynyl methanes

Joseph B Gianino1, Brandon L Ashfeld

  • 1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA.

Journal of the American Chemical Society
|October 23, 2012
PubMed
Summary

Titanocene dichloride (Cp(2)TiCl(2)) catalyzes a multicomponent coupling reaction. This method efficiently synthesizes diarylethynyl methanes, creating valuable all-carbon tertiary centers.

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