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LiCl-effect on asymmetric intramolecular hydroamination catalyzed by binaphthylamido yttrium complexes

Yulia Chapurina1, Régis Guillot, Dmitrii Lyubov

  • 1Equipe de Catalyse Moléculaire, Univ Paris-Sud, ICMMO, UMR 8182, Orsay, F-91405, France.

Dalton Transactions (Cambridge, England : 2003)
|October 23, 2012
PubMed

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One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
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