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Phosphorus flow and characterization in dry-grind corn ethanol plants.
A Alkan-Ozkaynak1, K G Karthikeyan
1Department of Biological Systems Engineering, University of Wisconsin, Madison, WI, USA.
Journal of Environmental Quality
|October 27, 2012
Summary
Corn ethanol coproducts like distillers grains with solubles (DDGS) contain high phosphorus. Understanding phosphorus flow and forms in DDGS is crucial for managing environmental impacts.
Area of Science:
- Agricultural Science
- Environmental Science
- Biochemistry
Background:
- High phosphorus (P) content and bioavailability in corn-ethanol coproducts (e.g., distillers grains with solubles, DDGS) can increase manure and soil P levels.
- These elevated P levels pose environmental risks, including eutrophication.
Purpose of the Study:
- To model total phosphorus mass flow to DDGS.
- To quantify the distribution of P into inorganic and phytase-hydrolyzable forms in coproducts.
- To inform strategies for phytase enzyme supplementation in corn-ethanol processing.
Main Methods:
- Detailed modeling of total phosphorus mass flow.
- Quantification of P distribution (inorganic vs. phytase-hydrolyzable) in thin stillage, DDGS, and modified DDGS (mDDGS).
- Evaluation of phytase enzyme efficacy in hydrolyzing nonorthophosphate P components.
Main Results:
- Corn accounts for 80.2% of P in coproducts, while yeast contributes 19.4%.
- Condensed solubles, despite lower mass, yield 70.9% of the P in DDGS.
- The phytase enzyme effectively hydrolyzed nonorthophosphate P in thin stillage, DDGS, and mDDGS.
Conclusions:
- Tracking P movement during corn-ethanol processing is essential for environmental management.
- Yeast and condensed solubles are significant P contributors in DDGS.
- Phytase supplementation is a viable strategy to reduce P bioavailability in corn-ethanol coproducts.
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