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The brave new world of coordination frameworks
1School of Chemistry, University of Nottingham, University Park, NG7 2RD, UK. Neil.Champness@nottingham.ac.uk
Summary
Coordination frameworks, including metal-organic frameworks (MOFs), were emerging in 1994. Early studies by Zaworotko and Ciani highlighted the intricate nature of these structures.
Area of Science:
- Materials Science
- Chemistry
Background:
- The field of coordination frameworks was nascent in 1994.
- Metal-organic frameworks (MOFs) were an emerging area of research derived from coordination frameworks.
Purpose of the Study:
- To highlight the early development and characteristics of coordination frameworks and MOFs.
- To showcase the foundational work by Zaworotko and Ciani in this field.
Main Methods:
- Review of foundational studies in coordination chemistry.
- Analysis of structural properties of early coordination frameworks.
Main Results:
- Demonstrated the foundational simplicity and complexity of coordination frameworks.
- Illustrated the potential of these structures in materials science.
Conclusions:
- Early research in 1994 laid the groundwork for the significant expansion of MOF science.
- The studies by Zaworotko and Ciani were pivotal in understanding the nature of these frameworks.
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