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Updated: May 17, 2026
Facet-to-facet Linking of Shape-anisotropic Colloidal Cadmium Chalcogenide Nanostructures
Published on: August 10, 2017
(2-Ethyl-2-oxazoline-κN)bis(N-ethyl-N-phenyl-dithio-carbamato-κ(2)S,S')cadmium
Damian C Onwudiwe1, Christien A Strydom, Eric C Hosten
1Chemical Resource Beneficiation, North-West University, Private Bag X6001, Potchefstroom 2520, South Africa.
Abstract:
In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(5)H(9)NO)], the Cd(II) atom is five-coordinated in a distorted square-pyramidal geometry by four S atoms from two chelating N-ethyl-N-phenyl dithio-carbamate ligands and one N atom from a 2-ethyl-2-oxazoline ligand. Inter-molecular C-H⋯π inter-actions are observed in the crystal structure.
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01:22EDTA: Chemistry and Properties
02:34Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can be...