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Updated: May 17, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
1-(3-Benzyl-4,6-dibenz-yloxy-2-hy-droxy-phen-yl)ethanone
Tania N Hill1, C-M Kuo, Barend C B Bezuidenhoudt
1Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.
Abstract:
The title compound, C(29)H(26)O(4), is essentially planar in the acetophenone portion that includes both the hy-droxy and a benz-yloxy O atoms, with an r.m.s. deviation of 0.0311 Å. The other two substituents inter-sect the plane at 70.45 (3) and 59.55 (4)°. In the molecule there is an intramolecular O-H⋯O hydrogen bond. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, as well as C-H⋯π and π-stacking inter-actions, with centroid-centroid distances 3.6570 (2) Å.
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