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Updated: May 17, 2026

Modification and Functionalization of the Guanidine Group by Tailor-made Precursors
Published on: April 27, 2017
3,5,3',5'-Tetra-methyl-4,4'-bi(1H-pyrazol-yl) hemihydrate
Shouwen Jin1, Yanfei Huang, Hao Fang
1Tianmu College of ZheJiang A & F University, Lin'An 311300, People's Republic of China.
Abstract:
In the title compound, C(10)H(14)N(4)·0.5H(2)O, the amino H atom of one of the two pyrazole rings is disordered over its two N atoms in a 1:1 ratio. The pyrazole rings are aligned at 60.1 (1)°. In the crystal, two bipyrazolyl mol-ecules are linked by an N-H⋯N hydrogen bond, generating a dimer; the dimer is connected to the water mol-ecule, which lies on a twofold rotation axis, resulting in the formation of a chain that makes an angle of ca 45.3 (1)° with the ab plane. The chains are cross-linked by N-H⋯O and O-H⋯N inter-actions, forming a three-dimensional network.

