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Related Experiment Video

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Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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Magnetic field enhanced structural instability in EuTiO3.

Z Guguchia1, H Keller, J Köhler

  • 1Physik-Institut der Universität Zürich, Winterthurerstraße 190, CH-8057 Zürich, Switzerland.

Journal of Physics. Condensed Matter : an Institute of Physics Journal
|November 7, 2012
PubMed
Summary
This summary is machine-generated.

Applying a magnetic field to Europium titanate (EuTiO3) shifts its structural phase transition to higher temperatures. This effect, driven by coupled spin-phonon interactions, aligns with theoretical predictions.

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Radio Frequency Magnetron Sputtering of GdBa2Cu3O7&#8722;&#948;/ La0.67Sr0.33MnO3 Quasi-bilayer Films on SrTiO3 (STO) Single-crystal Substrates
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Radio Frequency Magnetron Sputtering of GdBa2Cu3O7−δ/ La0.67Sr0.33MnO3 Quasi-bilayer Films on SrTiO3 (STO) Single-crystal Substrates

Published on: April 12, 2019

Area of Science:

  • Solid State Physics
  • Materials Science
  • Crystallography

Background:

  • Europium titanate (EuTiO3) exhibits a cubic to tetragonal structural phase transition at 282 K.
  • This transition is linked to oxygen octahedral rotations driven by acoustic mode softening.
  • No long-range magnetic order accompanies this structural change.

Purpose of the Study:

  • To investigate the influence of an external magnetic field on the structural phase transition temperature of EuTiO3.
  • To experimentally verify theoretical predictions regarding spin-phonon coupling in EuTiO3.

Main Methods:

  • Experimental application of external magnetic fields up to 9 Tesla.
  • Precise measurement of the structural phase transition temperature (T(S)) under varying magnetic fields.
  • Comparison of experimental results with theoretical models.

Main Results:

  • The structural phase transition temperature (T(S)) of EuTiO3 increases with the application of an external magnetic field.
  • A shift of approximately 4 K in T(S) was observed for a magnetic field of 9 Tesla.
  • The experimental findings are consistent with theoretical predictions.

Conclusions:

  • External magnetic fields can effectively tune the structural phase transition temperature in EuTiO3.
  • The observed magnetostructural coupling is attributed to interactions between spin, lattice anharmonicity, and phonons.
  • This study highlights the potential for magnetic fields to control structural properties in materials.