An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology
Tingzhi Liu1, Daibing Luo, Dingguo Xu
1College of Chemistry, Sichuan University, Chengdu 610064, PR China.
Dalton Transactions (Cambridge, England : 2003)
|November 20, 2012
Abstract:
Two new photoluminescent magnesium-based coordination polymers, Mg(int)(2)·H(2)O (1) and Mg(nt)(2) (2), were synthesized under solvothermal conditions. Structural analyses reveal that they have different 3,6-connected frameworks with rutile- and anatase-type topologies, respectively. Compound 1 remains stable after the removal of its guest molecules and it exhibits weak ferroelectric behavior.
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