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Updated: May 16, 2026

A Facile and Eco-friendly Route to Fabricate Poly(Lactic Acid) Scaffolds with Graded Pore Size
Published on: October 17, 2016
Facile route to an all-organic, triply threaded, interlocked structure by templated dynamic clipping
Andrew Pun1, David A Hanifi, Gavin Kiel
1The Molecular Foundry, Lawrence Berkeley National Laboratory, MS, USA.
Abstract:
Encaged! Three-terminal interlocked molecular species were obtained by dynamic (2+3) assembly of a cagelike macro-bicycle around a trifurcated trispyridinium π guest. The complex is stabilized by π-π interactions and multiple [C-H⋅⋅⋅O] and [C-H⋅⋅⋅N] interactions. Uncomplexed guest molecules cocrystallize alongside the threaded complexes in the solid state, thus giving extended π-stacked columns.
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