Related Experiment Video
Updated: May 16, 2026

Photoelectron Imaging of Anions Illustrated by 310 Nm Detachment of F−
Published on: July 27, 2018
Fluorescence emission of Ca-atom from photodissociated Ca2 in Ar-doped helium droplets. I. Experimental
A Masson1, M Briant, A Hernando
1Laboratoire Francis Perrin, CNRS-URA 2453, CEA, IRAMIS, Service des Photons Atomes et Molécules, F-91191 Gif-sur-Yvette Cedex, France.
Abstract:
The Ca(2) → Ca(4s4p(1)P) + Ca(4s(2)(1)S) photodissociation was investigated in a He droplet isolation experiment where the droplets are doped by Ar atoms. Fluorescence spectra associated with the Ca(4s4p(1)P → 4s(2)(1)S) emission were recorded as a function of the average number of Ar atoms per droplet. Three contributions were observed depending on whether the emitting Ca atoms are free, bound to helium atoms or bound to argon atoms. Moreover, the full Ca(4s4p(1)P → 4s(2)(1)S) fluorescence emission was recorded as a function of the wavelength of the photodissociation laser, hence providing the action spectrum of the Ca(2) → Ca(4s4p(1)P) + Ca(4s(2)(1)S) process. The latter spectrum suggests that in He droplets doped by argon, Ca atoms are attracted inside the droplet where they associate as Ca(2). Full analysis of the spectra indicate that the emission of Ca bound to a single Ar atom is redshifted by 94 cm(-1) with respect to the emission of free Ca.
More Related Videos
Related Concept Videos
Atomic Fluorescence Spectroscopy
Atomic Spectroscopy: Absorption, Emission, and Fluorescence
Atomic Emission Spectroscopy: Overview
Atomic Emission Spectroscopy: Lab
Atomic Emission Spectroscopy: Instrumentation
Inductively Coupled Plasma Atomic Emission Spectroscopy: Principle
The ions and electrons produced interact with the fluctuating magnetic field created by a water-cooled...

