Self-assembly of an octanuclear platinum(II) tetragonal prism from a new Pt(II)4 organometallic star-shaped acceptor and its nitroaromatic sensing study
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Updated: May 16, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
Sankarasekaran Shanmugaraju1, Harshal Jadhav, Yogesh P Patil
1Department of Inorganic and Physical Chemistry, Indian Institute of Sciences, Bangalore 560012, India.
Abstract:
[2 + 4] self-assembly of a pyrene-functionalized Pt(II)(8) tetragonal prism (2) is achieved using a newly designed star-shaped organometallic acceptor (1) in combination with an amide-based "clip" donor (L). The propensity of this prism (2) as a selective sensor for nitroaromatics (2,4-dinitrotoluene, 1,3,5-trinitrotoluene, and picric acid), which are the chemical constituents of many commercial explosives, has been examined.
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