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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...

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Optimized Fabrication Procedure for High-Quality Graphene-based Moiré Superlattice Devices
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Graphene-assisted critically-coupled optical ring modulator.

Michele Midrio1, Stefano Boscolo, Michele Moresco

  • 1Dipartimento di Ingegneria Elettrica Gestionale e Meccanica, Università degli Studi di Udine, 33100 Udine, Italy. midrio@uniud.it

Optics Express
|November 29, 2012
PubMed
Summary
This summary is machine-generated.

This study demonstrates a graphene-based optical modulator that controls light loss in a ring cavity. The device offers a 100 GHz bandwidth and low switching energy, compatible with CMOS technology.

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Area of Science:

  • Photonics
  • Materials Science
  • Electrical Engineering

Background:

  • Graphene exhibits tunable conductivity at optical frequencies due to carrier injection.
  • Optical modulators are crucial components in photonic integrated circuits.
  • Critical-coupling in optical cavities enables efficient light-matter interaction.

Purpose of the Study:

  • To propose and analyze a novel optical modulator utilizing graphene's tunable conductivity.
  • To leverage the critical-coupling concept for efficient optical modulation.
  • To assess the performance metrics, including bandwidth and switching energy, of the proposed modulator.

Main Methods:

  • Numerical simulations were employed to model the graphene-based optical modulator.
  • The critical-coupling theory was applied to design the ring cavity modulator.
  • Graphene's optical conductivity modulation was simulated by varying carrier injection.

Main Results:

  • A modulator with a bandwidth of 100 GHz was designed.
  • Switching energy was found to be in the order of few femtojoules per bit.
  • The modulator demonstrated potential for operation with driving voltages below 1.2 volts.

Conclusions:

  • The proposed graphene-based optical modulator is a viable device for high-speed optical signal processing.
  • Low switching energy and voltage requirements make it compatible with low-voltage CMOS technology.
  • This work opens avenues for advanced photonic devices integrated with graphene.