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NMR Spectrometers: Resolution and Error Correction01:14

NMR Spectrometers: Resolution and Error Correction

When magnetic nuclei in a sample achieve resonance and undergo relaxation, the signal detected in NMR is an approximately exponential free induction decay. Fourier transform of an exponential decay yields a Lorentzian peak in the frequency domain. Lorentzian peaks in an NMR spectrum are defined by their amplitude, full width at half maximum, and position, where the peak width is governed by the spin-spin relaxation time alone. In real experiments, however, the applied magnetic field is rendered...
Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
Atomic Absorption Spectroscopy: Interference01:25

Atomic Absorption Spectroscopy: Interference

Interference leads to systematic error in atomic absorption (AA) measurements by enhancing or diminishing the analytical signal or the background. These interferences can be grouped into three main categories: spectral interference, chemical interference, and physical interference.
Spectral interference occurs when signals from other elements or molecules overlap with the analyte signal, falsely elevating or masking the analyte's absorbance. This interference can be corrected using Zeeman,...
Distance Corrections01:15

Distance Corrections

To achieve precise distance measurements, especially in surveying and construction, certain corrections must be applied to account for potential sources of error like the standardization errors, temperature variations, and slope adjustments.Standardization error emerges when measurement equipment undergoes changes, such as wear, repairs, or weather impacts. To address this, surveyors compare the equipment’s readings to a standard. This process identifies any deviation that might lead to...
Interference and Diffraction02:18

Interference and Diffraction

Interference is a characteristic phenomenon exhibited by waves. When two electromagnetic waves interact with their peaks and troughs coinciding, a resulting wave with enhanced amplitude is produced. This is known as constructive interference. In this case, the two waves interacting are in phase with each other.
Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview01:13

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview

Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
The ATR process begins by directing a beam...

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Related Experiment Video

Updated: May 16, 2026

Controlled Synthesis and Fluorescence Tracking of Highly Uniform Poly(N-isopropylacrylamide) Microgels
11:34

Controlled Synthesis and Fluorescence Tracking of Highly Uniform Poly(N-isopropylacrylamide) Microgels

Published on: September 8, 2016

Aureolegraph internal scattering correction.

John DeVore1, Dennis Villanucci, Andrew LePage

  • 1Applied Physics Group, Visidyne, Inc., 429 Stanley Drive, Santa Barbara, California 93105, USA. devore@visidyne.com

Applied Optics
|December 5, 2012
PubMed
Summary

Two methods correct solar scattering measurements. Subtracting external occluding ball data is reliable, while modified Langley Plots are problematic due to changing atmospheric conditions.

Area of Science:

  • Atmospheric Science
  • Optical Remote Sensing

Background:

  • Accurate measurement of solar scattering by atmospheric particles is crucial for climate modeling.
  • Aureolegraph measurements are affected by instrumental scattering, requiring correction.

Purpose of the Study:

  • To present and evaluate two methods for determining instrumental scattering to correct aureolegraph measurements.
  • To assess the reliability of these correction methods for various atmospheric particulates.

Main Methods:

  • Method 1: Subtracting aureolegraph measurements made with and without an external occluding ball.
  • Method 2: Modifying the Langley Plot method by extrapolating measurements over a wide range of solar zenith angles.

Main Results:

  • The occluding ball method provided reliable scattering corrections for diverse atmospheric layers (aerosols, clouds).

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  • The modified Langley Plot method showed power-law dependencies but varied significantly (factor of 8), indicating issues with changing aerosol conditions.
  • Conclusions:

    • The external occluding ball method is a robust approach for correcting instrumental scattering in aureolegraph measurements.
    • The modified Langley Plot method is less reliable due to its sensitivity to dynamic atmospheric conditions.