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Updated: May 16, 2026

Exfoliation of Egyptian Blue and Han Blue, Two Alkali Earth Copper Silicate-based Pigments
Published on: April 24, 2014
Nanoscience of an ancient pigment
Darrah Johnson-McDaniel1, Christopher A Barrett, Asma Sharafi
1Department of Chemistry, University of Georgia, Athens, Georgia 30602-2556, United States.
Abstract:
We describe monolayer nanosheets of calcium copper tetrasilicate, CaCuSi(4)O(10), which have strong near-IR luminescence and are amenable to solution processing methods. The facile exfoliation of bulk CaCuSi(4)O(10) into nanosheets is especially surprising in view of the long history of this material as the colored component of Egyptian blue, a well-known pigment from ancient times.
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