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Related Concept Videos

Dielectric Polarization in a Capacitor01:31

Dielectric Polarization in a Capacitor

The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
The Electrical Double Layer01:30

The Electrical Double Layer

In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
Electrochemical Systems01:24

Electrochemical Systems

Electrochemical systems provide a fascinating insight into the dynamic interplay of charged species within various phases. One notable example is the interaction between a membrane permeable to K⁺ ions but not to Cl⁻ ions, separating an aqueous KCl solution from pure water. As K⁺ ions diffuse through the membrane, they generate net charges on each phase, leading to a potential difference between them.Similarly, when a piece of Zn is immersed in an aqueous ZnSO₄ solution, the Zn metal, composed...
Potential Due to a Polarized Object01:29

Potential Due to a Polarized Object

A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
Induced Electric Dipoles01:28

Induced Electric Dipoles

A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Electrostatic Boundary Conditions in Dielectrics01:27

Electrostatic Boundary Conditions in Dielectrics

When an electric field passes from one homogeneous medium to another, crossing the boundary between the two mediums imparts a discontinuity in the electric field. This results in electrostatic boundary conditions that depend on the type of mediums the field propagates through.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity.

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Updated: May 16, 2026

The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids
10:03

The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids

Published on: September 30, 2014

Maxwell-Wagner polarization and frequency-dependent injection at aqueous electrical interfaces.

Mitchell Desmond1, Nicholas Mavrogiannis, Zachary Gagnon

  • 1Department of Chemical and Biomolecular Engineering, Johns Hopkins University, 221 Maryland Hall, 3400 North Charles Street, Baltimore, Maryland 21218, USA.

Physical Review Letters
|December 11, 2012
PubMed
Summary

We discovered a new alternating current (AC) phenomenon causing frequency-dependent fluid displacement at liquid-liquid interfaces. The direction of fluid flow reverses based on electrical properties and AC frequency, explained by Maxwell-Wagner polarization.

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The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids
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Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone
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AC Electrokinetic Phenomena Generated by Microelectrode Structures
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AC Electrokinetic Phenomena Generated by Microelectrode Structures

Published on: July 28, 2008

Area of Science:

  • Electrokinetics
  • Fluid dynamics
  • Interfacial science

Background:

  • Liquid-liquid interfaces are crucial in microfluidics and chemical processes.
  • Controlling fluid behavior at these interfaces is essential for many applications.

Purpose of the Study:

  • To demonstrate a novel alternating current (AC) induced interfacial polarization and fluid displacement phenomenon.
  • To investigate the frequency-dependent nature of this fluid displacement at a liquid-liquid interface.

Main Methods:

  • Utilizing a microfluidic channel to flow two immiscible liquid streams side-by-side.
  • Applying an AC electric field perpendicular to the interface between the liquid lamellae.
  • Observing and analyzing fluid displacement across the interface as a function of AC frequency.

Main Results:

  • Demonstrated frequency-dependent fluid displacement at the liquid-liquid interface.
  • Observed high-conductivity fluid displacing into high-dielectric fluid at low frequencies.
  • Observed reversal of displacement (high-dielectric into high-conductivity) at high frequencies.

Conclusions:

  • The observed fluid displacement is a novel AC interfacial polarization phenomenon.
  • The crossover frequency for displacement reversal is governed by the electrical properties of the fluids.
  • Maxwell-Wagner polarization mechanics accurately explain the observed phenomenon.