[Mineralogical characteristics of biogenic schwertmannite amended with different pretreatment methods and the effects...

Biogenic schwertmannite has better absorption performance for As(III) than other adsorbents, but there is obvious agglomeration of mineral particles due to the polysaccharides secreted by the bacteria during the synthesis of schwertmannite. The aim of this study was to find out a best pretreatment method to further reduce the agglomeration of mineral particles and enhance the As(III) absorption capacity by comparing the effects of different pretreatment methods on the mineralogical characteristics and adsorption performance of schwertmannite. The pretreatment methods of the biogenic schwertmannite induding the treatments with NaOH, NaCl, thermal activation at 200 degrees C and ethanol-ultrasound. The results showed that the mineral phases were not altered after pretreatment, however, different physical and chemical properties of schwertmannite were found after different pretreatment methods were used. Compared with the original mineral, the mineral surface area, Fe/S molar ratio, SEM image and As(III) adsorption were significantly changed. The highest As(III) sorption capacity was obtained for the pH 12 NaOH treated schwertmannite with the maximum absorbance at room temperature increased from 101.9 mg x g(-1) to 143.3 mg x g(-1), and the surface area enhanced from 45.63 m2 x g(-1) to 325.18 m2 x g(-1). Besides, aggregation of mineral particles was remarkably decreased.