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Production of Membrane-Filtered Phase-Shift Decafluorobutane Nanodroplets from Preformed Microbubbles
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Stability of interfacial nanobubbles.

Xuehua Zhang1, Derek Y C Chan, Dayang Wang

  • 1Department of Chemical and Biomolecular Engineering, University of Melbourne, Melbourne VIC 3010, Australia. xuehuaz@unimelb.edu.au

Langmuir : the ACS Journal of Surfaces and Colloids
|December 14, 2012
PubMed
Summary

Interfacial nanobubbles shrink in degassed water and grow slightly in air-equilibrated water. Their long lifetimes are influenced by dissolved gas levels and a pinned three-phase boundary, slowing morphological changes.

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Area of Science:

  • Surface Science
  • Nanotechnology
  • Physical Chemistry

Background:

  • Interfacial nanobubbles (INBs) are nanoscale gas bubbles at a solid-liquid interface.
  • Their long lifetimes are intriguing but not fully understood, with ongoing debate on underlying mechanisms.
  • Existing theoretical models do not fully explain INB stability and evolution.

Purpose of the Study:

  • To investigate the morphological evolution of INBs under different dissolved gas conditions.
  • To elucidate the role of the three-phase boundary in INB stability and dynamics.
  • To provide a more comprehensive understanding of INB lifetimes and their dependence on environmental factors.

Main Methods:

  • Atomic force microscopy (AFM) was employed to visualize and track INB morphology.
  • Experiments were conducted in both air-equilibrated and partially degassed water.
  • Morphological changes and three-phase boundary behavior were analyzed over time.

Main Results:

  • INBs exhibited shrinkage in partially degassed water and slight growth in air-equilibrated water.
  • The three-phase boundary of the INBs remained pinned throughout their morphological evolution.
  • INB lifetime was found to be sensitive to dissolved gas saturation levels, particularly near saturation.

Conclusions:

  • The saturation level of dissolved gases significantly impacts INB stability and lifetime.
  • Pinning of the three-phase boundary is a critical factor that retards both INB growth and shrinkage kinetics.
  • A modified Epstein-Plesset model incorporating pinning effects was developed to explain observed INB dynamics.