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Sign-sensitive determination of heteronuclear dipolar coupling to spin-1 by selective decoupling.

B B Kharkov1, V I Chizhik, S V Dvinskikh

  • 1Department of Chemistry, Royal Institute of Technology KTH, Teknikringen 36, SE-10044 Stockholm, Sweden.

The Journal of Chemical Physics
|December 27, 2012
PubMed
Summary

This study introduces a novel nuclear magnetic resonance (NMR) technique for determining the sign of dipolar couplings. This method is crucial for understanding molecular structures, especially for rare spins with quadrupolar interactions.

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